SYNTHESIS AND CHARACTERIZATION OF COBALT(III) DITHIOCARBAMATE COMPLEXES

Abstract

Tris(N-(pyrrol-2-ylmethyl)-N-butyldithiocarbamato-S,S?)cobalt(III) (1),  tris(N-(pyrrol-2-ylmethyl)-N-(2-phenylethyl)dithiocarbamato-S,S?)cobalt(III) (2) and tris(N-methylferrocenyl-N-(2-phenylethyl)dithiocarbamato-S,S?)cobalt(III) (3) have been synthesized and characterized by elemental analysis and spectroscopy (IR,  UV-vis and NMR). The elemental analysis and IR, 1H and 13C NMR spectra are consistent with the formation of the cobalt(III) complexes with dithiocarbamate ligands.